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Contrast mechanism at landing energy near 0 eV in super low energy scanning electron microscopy.

In recent years, the technique of scanning electron microscopy (SEM) observation with low landing energy of a few keV or less has become common. We have especially focused on the drastic contrast change at near 0 eV. Using a patterned sample consisting of Si, Ni and Pt, threshold energies where total reflection of incident electrons occur was investigated by SEM at near 0 eV. In both the cases of in-situ and ex-situ sample cleaning, drastic changes in the brightness of each material were observed at near 0 eV, with threshold energies in the order Si < Ni < Pt. This order agreed with the order of the literature values of the work functions and the surface potentials measured by Kelvin force probe microscopy. This result suggests that the difference of the threshold energy is caused by the difference in surface potential due to the work function difference of each material. Although the order of the threshold energies also agreed with those of work functions reported in literatures, the work functions of air exposed surfaces should be rather considered as "modified work functions", since they could be significantly altered by the adsorbates etc. Nevertheless, the difference of threshold energy for each material was observed with commercial SEM at landing energy near 0 eV, which opens new possibility to distinguish materials, although the difference should be rather recognized as "fingerprints", since surface potentials are sensitive to conditions of surface treatments and atmospheric exposure. Mini-abstract In this study, we utilized a commercial SEM with near 0 eV landing energy to explore threshold energies where total reflection occurs for various materials in air-exposed model samples. Our results demonstrate the potential of threshold energy as a distinctive fingerprint for material differentiation.

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Effect of High Pressure Hydrogen Gas on Fatigue and Fracture Properties of API X65 LinepIpe Steels

Abstract Hydrogen is one of the promising energy carriers for achieving a carbon neutral society. The pipeline system is positioned as a major type of infrastructure which will be indispensable for mass transportation of gaseous hydrogen. It is acknowledged that existing natural gas pipelines can be used safely to transport hydrogen blends up to 10 or 20 %. However, it is also known that the mechanical properties of steels are significantly degraded by hydrogen embrittlement, even under small partial pressures of hydrogen. Material degradation is considered in the hydrogen pipeline code ASME B31.12. This code requires evaluation of the fracture and fatigue properties of linepipe materials used under hydrogen, and a critical assessment is conducted so that fracture of the pipeline can be avoided during its service life. In the present study, the hydrogen absorption properties, fracture toughness and fatigue crack growth properties under a 25 MPa hydrogen gas environment were investigated by using 3 kinds of linepipe steels manufactured by different methods. The materials were API X65 linepipe steel, which were manufactured as ERW, LSAW and seamless (SMLS) linepipes. Although all the materials showed a bainitic ferrite generally called, each microstructure had distinctive characteristics attributable to the manufacturing process. While all the linepipe steels showed better fracture toughness and fatigue crack growth rates than the ASME B. 31.12 design curve, their hydrogen absorption properties, fracture toughness in hydrogen gas and fatigue crack growth properties in hydrogen gas differed due to their crystal structures, even though the strength grade of the materials. In the steels used in this study, the fracture toughness and fatigue crack growth characteristics under a hydrogen atmosphere were insensitive to the influence of absorbed hydrogen, and were considered to be influenced by the material factors that determine the fracture toughness and fatigue crack growth characteristics in the atmosphere.

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